I just answered my own question
The reason why I couldn't find a rule regarding "hand in face" was because I was looking in the "Personal Fouls" section of the NCAA rulebook.
However, under "Technical Fouls," Rule 10-5, Article 3 states that a direct technical fould for unsporting player conduct will be charged for "Purposely obstructing an opponent's vision by waving or placing hand(s) near his or her eyes."
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