Deliberately aimed at the head with considerable force sounds like a good T. Throwing the ball off of someone is a legitimate play, but there's a case study on an officials judgement if they, say, throw it as hard as they can, purposely, at someone's head.
I've never had this happen in a game, but I can't see letting it go... especially in a situation where players are already on edge pushing and yacking away.
TLDR: Sounds like you made a judgement call and it was the right one.
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