Safety in both.
In NCAA, for the reasons mentioned above. Only kicking or batting a loose ball changes the ball's impetus (read: force in NF) if the ball is not at rest. If it is at rest, then any contact with it will be considered new impetus and therefore a TB. Of course there are a couple of exceptions like being blocked into the ball (when it's at rest), etc. but those really don't apply.
As for Fed, once the ball is grounded (at rest or not) we can have new force due to a muff. But again, it's got to be a clear attempt to gain possession. In mcrowder's case, ricocheting off of R's helmet doesn't change force, and certainly not if the ball hasn't been grounded yet. If it had been grounded, and it bounced off of R's helmet as he was reaching for it then I'd have to think long and hard about it, but if he didn't know what hit him, then he couldn't have been trying to gain possession and therefore it's not a muff--no new force so it's a safety. Just remember that in Fed, merely touching or contact is not necessarily a muff.
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