Charles's out is in effect nullified by the appeal. Charles can't be put out twice in any of the various corollaries mentioned - but his out can change from being the 2nd out to being the 3rd out, and in the case of the OP, it matters.
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"Many baseball fans look upon an umpire as a sort of necessary evil to the luxury of baseball, like the odor that follows an automobile." - Hall of Fame Pitcher Christy Mathewson
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